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Purity:99%
The preparation and physico-chemical cha...
Although significant progress has been m...
The construction of molecular catalysts ...
Three significant modifications to exist...
pyrrole
4-Phenylbenzaldehyde
5,10,15,20-tetrakis((1,1′-biphenyl)-4-yl)porphyrin
| Conditions | Yield |
|---|---|
|
With
air; nitrobenzene; valeric acid;
at 129 ℃;
for 1h;
|
46% |
|
With
zinc diacetate; oxygen;
In
acetic acid; nitrobenzene;
for 1h;
Reflux;
|
8.5% |
|
pyrrole; 4-Phenylbenzaldehyde;
With
trifluoroacetic acid;
In
dichloromethane;
at 20 ℃;
for 1h;
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
at 20 ℃;
for 1.5h;
|
7% |
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
phenylboronic acid
5,10,15,20-tetrakis((1,1′-biphenyl)-4-yl)porphyrin
| Conditions | Yield |
|---|---|
|
With
potassium carbonate;
In
5,5-dimethyl-1,3-cyclohexadiene;
at 100 ℃;
for 24h;
Reagent/catalyst;
|
94% |
pyrrole
4-Phenylbenzaldehyde
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
phenylboronic acid
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