pd_meltingpoint:-61.15°C (estimate)
Purity:99%
InChI:InChI=1/C8H18O/c1-4-8(6-9)5-7(2)3/h7-9H,4-6H2,1-3H3
The paper is devoted to a study of the r...
A novel class of 19 carbamates was synth...
Alkanes can be functionalized with high ...
4-Methyl-1-pentene
triethylaluminum
2-ethyl-4-methyl-1-pentanol
(2S)-2-isobutyl-1,4-butanediol
(2R)-2-isobutyl-1,4-butanediol
Conditions | Yield |
---|---|
4-Methyl-1-pentene; triethylaluminum; With (p-S)(p-S)-bis[η5-[1-[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]indenyl]]zirconium dichloride; In cyclohexane; at 22 ℃; for 24h; Inert atmosphere; Schlenk technique;
With oxygen; In cyclohexane; at 0 ℃; for 26h;
With hydrogenchloride; water; In cyclohexane; at 0 ℃; enantioselective reaction;
|
25 % ee |
4-Methyl-1-pentene; triethylaluminum; With (p-S)-(η5-cyclopentadienyl)[η5-[1-[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]indenyl]]zirconium dichloride; In benzene; at 22 ℃; for 24h; Inert atmosphere; Schlenk technique;
With oxygen; In benzene; at 0 ℃; for 26h;
With hydrogenchloride; water; In benzene; at 0 ℃; enantioselective reaction;
|
12 % ee |
2-ethyl-4-methyl-1-pentanol
Conditions | Yield |
---|---|
With kieselguhr; nickel; at 120 ℃; under 147102 Torr; Hydrogenation;
|
methanol
2-Methylhexane
4-Methylpentanoic acid
2-ethyl-4-methylpentanoic acid
(2-Ethyl-4-methyl-pentyloxysulfonyl)-phenyl-acetic acid
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