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pd_meltingpoint:170 °C
Purity:99%
InChI:InChI=1/C44H26Br4N4/c45-29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(46)12-4-26)37-21-23-39(51-37)44(28-7-15-32(48)16-8-28)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(47)14-6-27/h1-24,49-50H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-
Palladium catalyzed cross coupling react...
The new porphyrin-based tetraphosphonic ...
Hydrogen-bonded organic frameworks (HOFs...
The symmetrical meso-tetrasubstituted po...
Single-crystal electron diffraction has ...
A novel dianhydride 3,3’-bis(3,4-dicarbo...
This study targets the construction of p...
The absence of a secure long-term sustai...
Porous carbon materials have been widely...
A new general and green synthetic protoc...
The Pd-catalyzed carbonylation of Br-sub...
The synthesis of 5,10,15,20-tetrakis [4 ...
A novel conjugated microporous polymer w...
This study concerns the synthesis of 5,1...
In this study, a novel asymmetrically me...
Several 3,5-dibromo substituted BODIPY (...
A BODIPY derivative (compound 2), substi...
5,10,15,20-tetrakis-(4-bromo-phenyl)-porphyrinogene
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
| Conditions | Yield |
|---|---|
|
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane; toluene;
|
|
|
With
air;
In
dichloromethane;
at 39 ℃;
for 4h;
|
|
|
With
air;
In
dichloromethane;
at 39 ℃;
|
|
|
With
air;
In
dichloromethane;
at 39 ℃;
for 3h;
|
|
|
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
for 2h;
Inert atmosphere;
Darkness;
|
135 mg |
|
With
ammonium cerium (IV) nitrate;
In
dichloromethane;
at 20 ℃;
for 0.333333h;
Green chemistry;
|
|
|
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
for 0.0833333h;
Inert atmosphere;
|
tetrakis(4-aminophenyl)porphyrin
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
| Conditions | Yield |
|---|---|
|
With
hydrogen bromide; sodium nitrite;
Yield given. Multistep reaction;
1)5 deg C, 2)100 deg. C;
|
|
|
tetrakis(4-aminophenyl)porphyrin;
With
hydrogenchloride; sodium nitrite;
In
water;
for 0.166667h;
Cooling with ice;
With
potassium bromide;
In
water;
at 20 ℃;
for 2.83333h;
Cooling with ice;
|
pyrrole
4-bromo-benzaldehyde
4-methoxy-benzaldehyde
tetrakis(4-aminophenyl)porphyrin
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