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diazoacetic acid ethyl ester
cyclo-octa-1,5-diene
C12H18O2
C12H18O2
| Conditions | Yield |
|---|---|
|
With
copper acetylacetonate;
In
ethyl acetate;
Reflux;
|
58% 8.1% |
|
dirhodium tetraacetate;
In
dichloromethane;
at 0 ℃;
|
33.3 % de |
|
With
2CF3O3S(1-)*C43H49Cu2Fe2N6O2(2+);
In
dichloromethane;
at 25 ℃;
for 10.5h;
optical yield given as %de;
Inert atmosphere;
|
|
|
With
dirhodium tetraacetate;
In
dichloromethane;
at 0 - 20 ℃;
for 48h;
Overall yield = 88 %; Overall yield = 6.979 g;
Inert atmosphere;
|
|
|
With
dirhodium tetraacetate;
at 20 ℃;
for 25h;
|
cyclo-octa-1,5-diene
C12H18O2
| Conditions | Yield |
|---|---|
|
With
rhodium(II) acetate;
|
diazoacetic acid ethyl ester
cyclo-octa-1,5-diene
(1α,8α,9α)-bicyclo[6.1.0]non-4-yn-9-ylmethyl (4-nitrophenyl)carbonate
C10H16O
(1α,8α,9α)-bicyclo[6.1.0]non-4-yn-9-ylmethanol
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