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14074-80-7

  • Product Name:ZINC MESO-TETRAPHENYLPORPHINE
  • Molecular Formula:C44H28 N4 Zn
  • Molecular Weight:678.123
  • Appearance:purple crystalline powder
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Product Details

pd_meltingpoint:>350 °C (decomp)

Appearance:purple crystalline powder

Purity:99%

Chemical plants supply high-quality ZINC MESO-TETRAPHENYLPORPHINE 14074-80-7 in bulk

  • Molecular Formula:C44H28 N4 Zn
  • Molecular Weight:678.123
  • Appearance/Colour:purple crystalline powder 
  • Melting Point:>350 °C (decomp) 
  • Boiling Point:°Cat760mmHg 
  • Flash Point:°C 
  • PSA：34.58000 
  • Density:g/cm3 
  • LogP:6.43530 

ZINC MESO-TETRAPHENYLPORPHINE(Cas 14074-80-7) Usage

Purification Methods

Purify the porphyrin by chromatography on neutral (Grade I) alumina, followed by recrystallisation from CH2Cl2/MeOH [Yamashita et al. J Phys Chem 91 3055 1987].

InChI:InChI=1/C44H30N4.Zn/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32;/h1-28,45,48H;/q;+2/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-;

14074-80-7 Relevant articles

Selective nitrogen reduction to ammonia on iron porphyrin-based single-site metal-organic frameworks

Cong, Meiyu,Chen, Xuyang,Xia, Kai,Ding, Xin,Zhang, Linlin,Jin, Yu,Gao, Yan,Zhang, Lixue

, p. 4673 - 4678 (2021)

Constructing efficient catalysts for N2r...

Turn on fluorescence sensing of vapor phase electron donating amines via tetraphenylporphyrin or metallophenylporphrin doped polyfluorene

He, Chao,He, Qingguo,Deng, Changmin,Shi, Liqi,Zhu, Defeng,Fu, Yanyan,Cao, Huimin,Cheng, Jiangong

, p. 7536 - 7538 (2010)

A sensitive, selective, reversible, and ...

CHEMICAL DEGRADATION OF GAS-SENSING MESO-TETRA-ARYLPORPHIN THIN FILMS BY HIGH LEVELS OF DINITROGEN TETROXIDE.

Honeybourne, Colin L.,Hill, Callum A. S.

, p. 315 - 322 (1988)

Thin solid films of free base meso-tetra...

Laser-power-dependent Coordination and Photo-oxidation of Zinc Tetraphenylporphin in Alkyl Chlorides probed by Resonance Raman Spectroscopy

Saini, G. S. S.,Chaudhury, N. K.,Verma, A. L.

, p. 2853 - 2858 (1992)

Changes in the axial ligation and ?-cati...

Tetraphenylporphyrin picks up zinc atoms from a silver surface

Kretschmann, Andreas,Walz, Marie-Madeleine,Flechtner, Ken,Steinrueck, Hans-Peter,Gottfried, J. Michael

, p. 568 - 570 (2007)

We demonstrate that adsorbed meso-tetrap...

Electron transfer at liquid/liquid interfaces. The effects of ionic adsorption, electrolyte concentration, and spacer length on the reaction rate

Liu, Biao,Mirkin, Michael V.

, p. 3933 - 3940 (2002)

Several factors affecting the rate of he...

Microwave assisted synthesis of meso-tetraphenylporphyrin and its application for trace metal spectrophotometric determination

Givianrad,Bahrami

, p. 6102 - 6104 (2013)

The synthesis of meso-tetraphenylporphyr...

The doubly oxidized, antiaromatic tetraphenylporphyrin complex [Li(TPP)][BF4]

Cissell, Julie A.,Vaid, Thomas P.,Yap, Glenn P. A.

, p. 2401 - 2404 (2006)

Oxidation of dilithium tetraphenylporphy...

Synthesis, chemical stability, and electrocatalytic properties of zinc(II) and cobalt(II) complexes of N-methyltetraphenylporphine

Berezin,Txao, Vu Thi,Azorina,Shukhto,Guseinov,Berezina

, p. 1267 - 1274 (2015)

Distortion of flat ligand structure in m...

Synthesis and photophysical properties of novel pyrene-metalloporphyrin dendritic systems

Rojas-Montoya, Sandra M.,Vonlanthen, Mireille,Porcu, Pasquale,Flores-Rojas, Gabriel,Ruiu, Andrea,Morales-Morales, David,Rivera, Ernesto

, p. 10435 - 10447 (2019)

A novel series of dendronized porphyrins...

Comparative in vitro Studies of the Topoisomerase I Inhibition and Anticancer Activities of Metallated N-Confused Porphyrins and Metallated Porphyrins

D'yakonov, Vladimir A.,Dzhemilev, Usein M.,Dzhemileva, Lilya U.,Halder, Nyancy,Ramazanov, Ilfir R.,Rath, Harapriya

, (2020)

Using the original approach, a series of...

Some peculiarities of metal exchange reactions in porphyrin and phthalocyanine complexes

Berezin,Shukhto,Nikol'skaya,Berezin

, p. 95 - 100 (2005)

Kinetics of metal exchange reaction Cd(I...

Isoporphyrins. Near-Infrared Dyes with Noticeable Photochemical and Redox Properties

Takeda, Yoshihiko,Takahara, Shigeru,Kobayashi, Yoshiko,Misawa, Hiroaki,Sakuragi, Hirochika,Tokumaru, Katsumi

, p. 2103 - 2106 (1990)

An isoporphyrin prepared by the action o...

Oxidative degradation of zinc porphyrin in comparison with its iron analogue

Bhuyan, Jagannath,Sarkar, Sabyasachi

, p. 10649 - 10652 (2010)

(Figure Presented) Solar conversion: Zin...

Observations on the Mechanochemical Insertion of Zinc(II), Copper(II), Magnesium(II), and Select Other Metal(II) Ions into Porphyrins

Atoyebi, Adewole O.,Brückner, Christian

, p. 9631 - 9642 (2019)

Building on a proof of concept study tha...

Synthesis of new porphyrin/fullerene supramolecular assemblies: A spectroscopic and electrochemical investigation of their coordination equilibrium in solution

Santos, Leandro J.,Carvalhoda-Silva, Dayse,Rebouas, Júlio S.,Alves, Marcos R.A.,Idemori, Ynara M.,Matencio, Tulio,Freitas, Rossimiriam P.,Alves, Rosemeire B.

, p. 228 - 235 (2011)

Two new fullerene ligands have been desi...

SPECTRAL COSENSITIZATION IN PHTHALOCYANINE-PORPHYRIN PHOTOELECTROCHEMICAL CELLS.

Perrier,Gauthier,Dao

, p. 598 - 602 (1988)

An organic multilayer photoelectrochemic...

Selective detection of DABCO using a supramolecular interconversion as fluorescence reporter

Paul, Indrajit,Samanta, Debabrata,Gaikwad, Sudhakar,Schmittel, Michael

, p. 1371 - 1378 (2019)

The quantitative double self-sorting bet...

Zinc(II) Complex of Meso-Tetraphenylporphyrin with 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II)

Obaleye, Joshua A.,Tella, Adedibu C.,Obiyenwa, Gabriel K.,Simon, Nzikahyel,Olawale, Margaret D.

, p. 589 - 595 (2016)

4-Methoxyaniline-5,10,15,20-tetraphenylp...

Synthesis and Spectral and Coordination Properties of meso-Tetraarylporphyrins

Ivanova, Yu. B.,Semeikin,Pukhovskaya,Mamardashvili, N. Zh.

, p. 1878 - 1883 (2019)

5,10,15,20-Tetrakis(3,5-dibromophenyl)po...

Synthetic Iron Porphyrins for Probing the Differences in the Electronic Structures of Heme a3, Heme d, and Heme d1

Amanullah, Sk,Saha, Paramita,Saha, Rajat,Dey, Abhishek

, p. 152 - 164 (2019)

A variety of heme derivatives are pervas...

Theoretical study of electronic structure and absorption spectra of diacid and zinc species of series of meso-phenylporphyrins

Zhang, Ying-Hui,Zhao, Li-Hong,Ruan, Wen-Juan,Xu, Yao

, p. 1449 - 1460 (2011)

DFT and TDDFT calculations with density ...

Spectral investigations of meso -tetraalkylporphyrin-fullerene host-guest complexes

Grover, Nitika,Rathi, Pinki,Sankar, Muniappan

, p. 997 - 1006 (2015)

Meso-tetraalkylporphyrins and their Zn(I...

Metal exchange in cadmium porphyrins with spatially shielded coordination centers

Berezin,Lazareva,Shukhto,Kumeev,Semeikin

, p. 1052 - 1057 (2013)

Shielding of coordination centers in met...

One-pot general synthesis of metalloporphyrins

Kumar, Anil,Maji, Suman,Dubey, Prashant,Abhilash,Pandey, Sohini,Sarkar, Sabyasachi

, p. 7287 - 7290 (2007)

A new general one-pot method for the syn...

Chemical infiltration during atomic layer deposition: metalation of porphyrins as model substrates

Zhang, Lianbing,Patil, Avinash J.,Li, Le,Schierhorn, Angelika,Mann, Stephen,Goesele, Ulrich,Knez, Mato

, p. 4982 - 4985 (2009)

New uses for ALD: By applying standard m...

Specific features of the formation of zinc and cadmium complexes with tetraphenylporphine in amphiprotic media

Kononov,Trifonova,Aleksandriiskii,Burmistrov,Koifman

, p. 413 - 416 (2009)

The kinetics of the complex formation re...

Kinetic control of the transmetalation of labile metalloporphyrins in individual and mixed solvents

Berezin,Shukhto,Lazareva

, p. 744 - 750 (2012)

Transmetalation reactions of cadmium com...

Chelation and fluorescence properties of tetraphenylporphyrin and 5,10,15,20-tetra(4-hydroxyphenyl)porphyrin in acetonitrile

Ivanova, Yu. B.,Parfenov,Mamardashvili, N. Zh.

, (2017)

The kinetics of complex formation betwee...

Zinc porphyrin-anthraquinonylimidazole supramolecular dyads

Sabuzi, Federica,Coletti, Alessia,Conte, Valeria,Floris, Barbara,Galloni, Pierluca

, p. 850 - 859 (2020)

In this work, the synthesis and spectros...

Preparation and characterization of SDS-stabilized hydrophobic porphyrinic nanoaggregates in water

Maqueira,Iribarren,Valdés,De Meloc, Celso P.,Dos Santos, Clécio G.

, p. 267 - 272 (2012)

Porphyrin nanoaggregates formed in the i...

Understanding ion sensing in Zn(II) Porphyrins: Spectroscopic and computational studies of nitrite/nitrate binding

Whittington, Christi L.,Maza, William A.,Woodcock, H. Lee,Larsen, Randy W.

, p. 4756 - 4762 (2012)

The development of effective sensor elem...

Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones

Campos, Vinicius R.,Gomes, Ana T. P. C.,Cunha, Anna C.,Neves, Maria Da Gra?a P. M. S.,Ferreira, Vitor F.,Cavaleiro, José A. S.

, p. 195 - 202 (2017)

This work describes a new approach to ob...

Solventless mechanochemical metallation of porphyrins

Ralphs, Kathryn,Zhang, Chen,James, Stuart L.

, p. 102 - 105 (2017)

A fast solvent-free method for the metal...

Simple electrochemical procedure for measuring the rates of electron transfer across liquid/liquid interfaces formed by coating graphite electrodes with thin layers of nitrobenzene

Shi, Chunnian,Anson, Fred C.

, p. 9850 - 9854 (1998)

A simple, new method is described that a...

Controlled morphogenesis of organic polyhedral nanocrystals from cubes, cubooctahedrons, to octahedrons by manipulating the growth kinetics

Kang, Longtian,Fu, Hongbing,Cao, Xinqiang,Shi, Qiang,Yao, Jiannian

, p. 1895 - 1901 (2011)

Morphological control of organic nanocry...

A general and efficient palladium-catalyzed intramolecular cyclization reaction of β-brominated porphyrins

Shen, Dong-Mei,Liu, Chao,Chen, Qing-Yun

, p. 6508 - 6511 (2006)

A general and efficient synthesis of fus...

Coordination of N-substituted porphyrins with simple and chelate zinc salts in DMSO

Berezin,Zharnikova,Andrianov,Shatunov,Semeikin

, p. 325 - 332 (2002)

The effect of peripheral substitution in...

Femtosecond dynamics of metalloporphyrins: Electron transfer and energy redistribution

Yu,Baskin,Steiger,Wan,Anson,Zewail

, p. 1 - 8 (1998)

Femtosecond-resolved, real-time dynamics...

-

Lee et al.

, p. 2685 (1976)

-

Thermophysical and structural properties of crystalline solvates of tetraphenylporphyrin and their zinc, copper and cadmium metallo-complexes

Perlovich, German L.,Zielenkiewicz, Wojciech,Kaszkur, Zbigniew,Utzig, Eva,Golubchikov, Oleg A.

, p. 163 - 171 (1998)

The results of a thermochemical and stru...

Origin of the hydrogen-deuterium kinetic isotope effect for porphyrin metalation

Lavallee, David K.,Onady, Gary M.

, p. 907 - 909 (1981)

It has been previously observed that the...

Reaction of metal exchange of cadmium 5,10,15,20-tetraphenylporphyrinate and its β-bromo derivative with zinc acetate in dimethylformamide

Zvezdina,Chizhova,Mamardashvili

, p. 989 - 992 (2013)

Metal exchange of cadmium 5,10,15,20-tet...

Synthesis and study of fluorine-functionalized ZnTPPs

Bartynski, Robert,Galoppini, Elena,Rangan, Sylvie,Viereck, Jonathan,Zhang, Yang

, (2022/03/09)

Five fluorinated zinc tetraphenyl porphy...

Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins

Shen, Hai M.,Ye, Hong L.,Wang, Qin,Hu, Meng Y.,Liu, Lei,She, Yuan B.

, p. 314 - 322 (2021/04/09)

A novel and efficient protocol for oxida...

14074-80-7 Process route

C<sub>44</sub>H<sub>28</sub>N<sub>4</sub><sup>(2-)</sup>*2C<sub>5</sub>H<sub>10</sub>N<sub>2</sub>*Zn<sup>(2+)</sup>

C44H28N4(2-)*2C5H10N2*Zn(2+)

zinc 5,10,15,20-tetraphenylporphyrin
14074-80-7

zinc 5,10,15,20-tetraphenylporphyrin

3-dimethylaminopropiononitrile
1738-25-6

3-dimethylaminopropiononitrile

Conditions
Conditions Yield
In benzene; at 298.15 ℃; Further Variations:; Solvents; Equilibrium constant;
acetonitrile*zinc(II)tetraphenylporphyrin

acetonitrile*zinc(II)tetraphenylporphyrin

zinc 5,10,15,20-tetraphenylporphyrin
14074-80-7

zinc 5,10,15,20-tetraphenylporphyrin

acetonitrile
75-05-8,26809-02-9

acetonitrile

Conditions
Conditions Yield
In benzene; at 298.15 ℃; Further Variations:; Solvents; Equilibrium constant;

14074-80-7 Upstream products

  • 917-23-7
    917-23-7

    5,15,10,20-tetraphenylporphyrin

  • 917-23-7
    917-23-7

    5,10,15,20-tetraphenyl-21H,23H-porphine

  • 5970-45-6
    5970-45-6

    zinc(II) acetate dihydrate

  • 557-34-6
    557-34-6

    zinc diacetate

14074-80-7 Downstream products

  • 22124-32-9
    22124-32-9

    5,10,15,20-tetraphenylporphyrine dihydrochloride

Relevant Products

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