
pd_meltingpoint:212-214°C
Purity:99%
|
Purification Methods |
Solanidine crystallises from CHCl3/MeOH, aqueous EtOH or aqueous MeOH as needles. TLC on Al2O3 plates using CH2Cl2/MeOH (98:2) gives a spot at RF 0.47. The hydrochloride crystallises from aqueous EtOH with m 345o(dec). The acetate crystallises from EtOH with m 208o. [Schreiber & Roensch Tetrahedron 21 6451965, Kessar et al. Tetrahedron 27 2153 1971, Reichestein & Reich Ann Rev Biochem 15 155 1946, Beilstein 21 III/IV 1398, 27 III/IV 2000.] |
InChI:InChI=1/C27H43NO/c1-16-5-8-23-17(2)25-24(28(23)15-16)14-22-20-7-6-18-13-19(29)9-11-26(18,3)21(20)10-12-27(22,25)4/h6,16-17,19-25,29H,5,7-15H2,1-4H3
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A divergent synthesis of solanidine and ...
A concise asymmetric synthesis of two na...
Demissidine and solanidine, two steroida...
Potato tubers accumulate varying amounts...
β-Chaconine
β-D-glucose
β-L-rhamnose
Solanidine
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
In
ethanol;
at 100 ℃;
for 3h;
Product distribution;
|
|
|
With
hydrogenchloride;
In
ethanol;
at 100 ℃;
for 3h;
|
Stenanthine
β-D-glucose
β-L-rhamnose
Solanidine
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
In
ethanol;
at 100 ℃;
Product distribution;
|
solanidine 3-O-α-L-rhamnopyranosyl-(1<*>2)-O-<β-D-glucopyranosyl-(1<*>4)>-β-D-glucopyranoside
solanidine 3-O-α-L-rhamnopyranosyl-(1->2)-β-D-glucopyranoside
C30H47NO5S
α-chaconine
3β(p-toluenesulfonyloxy)-22αH,25βH-solanid-5-en-3-ol
demissidine
3α,5-cyclo-5α,22αH,25βH-solanidan-6β-ol
solanidine β-D-galactopyranoside
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