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Purity:99%
InChI:InChI=1/C14H18O4/c1-9(2)17-13(15)11-5-7-12(8-6-11)14(16)18-10(3)4/h5-10H,1-4H3
[Problem] catalyst and the presence of c...
Carbon monoxide (CO) and styrene derivat...
The invention discloses a preparation me...
Half-sandwich complexes [Cp(PiPr3)Ru(CH3...
terephthaloyl chloride
isopropyl alcohol
terephthalic acid diisopropyl ester
Conditions | Yield |
---|---|
With
dmap; triethylamine;
In
dichloromethane;
at 20 ℃;
for 0.5h;
|
72% |
para-diiodobenzene
terephthalaldehyde,
isopropyl alcohol
terephthalic acid diisopropyl ester
Conditions | Yield |
---|---|
terephthalaldehyde,;
With
palladium 10% on activated carbon; sodium carbonate;
In
isopropyl alcohol;
at 120 ℃;
for 24h;
Inert atmosphere;
para-diiodobenzene; isopropyl alcohol;
With
triphenylphosphine;
In
1-methyl-pyrrolidin-2-one;
at 100 ℃;
for 24h;
Inert atmosphere;
|
56% |
1,4-benzenedicarboxylic acid dimethyl ester
isopropyl alcohol
carbon monoxide
isopropyl 4-iodobenzoate
terephthalic acid monoisopropyl ester
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