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pd_meltingpoint:183-186 °C
Purity:99%
InChI:InChI=1/C13H16O6/c14-6-9(15)11(17)12-10(16)7-18-13(19-12)8-4-2-1-3-5-8/h1-6,9-13,15-17H,7H2/t9-,10+,11+,12+,13?/m0/s1
PROBLEM TO BE SOLVED: To provide a metho...
The direct asymmetric self-aldol reactio...
A mild, regioselective deprotection of t...
The conformational preferences of two se...
D-Glucose
benzaldehyde dimethyl acetal
4,6-O-benzylidene-D-glucopyranose
| Conditions | Yield |
|---|---|
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
|
83% |
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 55 ℃;
|
71% |
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 60 ℃;
for 6h;
|
53.7% |
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 60 ℃;
reduced pressure;
|
|
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 50 ℃;
|
D-glucose
benzaldehyde dimethyl acetal
4,6-O-benzylidene-D-glucopyranose
| Conditions | Yield |
|---|---|
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
at 70 ℃;
|
D-Glucose
benzaldehyde
alpha-D-glucopyranose
benzaldehyde dimethyl acetal
acetyl 2,3-di-O-acetyl-4,6-O-benzyliden-D-glucopyranoside
1,2,3-tri-O-acetyl-4,6-O-benzylidene-β-D-glucopyranose
1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside
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