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Purity:99%
Permanent porosity in lantern-type M4L4 ...
A systematic exploration of the assembly...
dimethyl 3,3'-(pyridine-2,6-diyl)dibenzoate
3,3′-(pyridine-2,6-diyl)dibenzoic acid
Conditions | Yield |
---|---|
dimethyl 3,3'-(pyridine-2,6-diyl)dibenzoate;
With
sodium hydroxide;
In
tetrahydrofuran; methanol; water;
at 50 ℃;
With
hydrogenchloride;
In
tetrahydrofuran; methanol; water;
|
92% |
With
sodium hydroxide;
In
water;
at 100 ℃;
|
2,6-Dibromopyridine
3,3′-(pyridine-2,6-diyl)dibenzoic acid
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps
1: potassium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / tetrahydrofuran; water / 80 °C / Inert atmosphere; Sealed tube
2: sodium hydroxide / water / 100 °C
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; sodium hydroxide;
In
tetrahydrofuran; water;
|
dimethyl 3,3'-(pyridine-2,6-diyl)dibenzoate
2,6-Dibromopyridine
[3-(methoxycarbonyl)phenyl]boronic acid
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