
pd_meltingpoint:300 °C
Appearance:purple glistening crystalline powder
Purity:99%
|
Purification Methods |
Purify TPP by chromatography on neutral (Grade I) alumina, and recrystallisation from CH2Cl2/MeOH or *C6H6. It forms complexes with metals. [Yamashita et al. J Phys Chem 91 3055 1987, Beilstein 26 III/IV 1958.] |
InChI:InChI=1/C44H30N4/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32/h1-28,45,48H/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-
Abstract: Basic properties of 5,10,15,20...
The invention discloses a method for syn...
The invention relates to a tetraphenylpo...
The push-pull electronic and steric effe...
5,5'-bis(hydroxyphenylmethyl)bipyrrole
5-phenyldipyrromethane
5,15,10,20-tetraphenylporphyrin
benzaldehyde
5,10,15,20-Triphenylcorrole
| Conditions | Yield |
|---|---|
|
With
dysprosium(III) trifluoromethanesulfonate;
at 20 ℃;
Reagent/catalyst;
Solvent;
Concentration;
Time;
Reactivity;
|
9.8 %Spectr. 5.4 %Spectr. 4 %Chromat. |
2,2'-bipyrrole
1,9-bis-benzoyl-5-phenyldipyrromethane
meso-hexaphenyl[34]octaphyrin(1.1.1.0.1.1.1.0)
5,15,10,20-tetraphenylporphyrin
benzaldehyde
| Conditions | Yield |
|---|---|
|
With
ytterbium(III) triflate;
at 20 ℃;
Reagent/catalyst;
Solvent;
Concentration;
Reactivity;
|
6.7 %Spectr. 1.8 %Spectr. 18 %Chromat. |
pyrrole
benzaldehyde
pyridine-4-carbaldehyde
p-benzyloxybenzaldehyde
meso-tetraphenylchlorin
C46H32N4O
(5Z,10Z,14Z,19Z)-5,10,15,20-Tetraphenyl-porphyrin; compound with 4-nitro-phenol
N,N'-ethoxymethylene-meso-tetraphenylporphyrin
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