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Purity:99%
InChI:InChI=1/C12H20O2Si/c1-9-11(3,4)13-15(7,8)14-12(5,6)10-2/h1-2H,3-8H3
The synthesis of three 14-membered ring ...
dimethylsilicon dichloride
2-methyl-but-3-yn-2-ol
3,3,5,5,7,7-hexamethyl-4,6-dioxa-5-silanona-1,8-diyne
| Conditions | Yield |
|---|---|
|
With
dmap; triethylamine;
In
dichloromethane;
at 0 - 20 ℃;
|
63% |
benzophenone
3,3,5,5,7,7-hexamethyl-4,6-dioxa-5-silanona-1,8-diyne
1,11-dihydroxy-4,4,6,6,8,8-hexamethyl-1,1,11,11-tetraphenyl-5,7-dioxa-6-silaundeca-2,9-diyne
| Conditions | Yield |
|---|---|
|
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -40 - 20 ℃;
|
78% |
dimethylsilicon dichloride
2-methyl-but-3-yn-2-ol
1,11-dihydroxy-4,4,6,6,8,8-hexamethyl-1,1,11,11-tetraphenyl-5,7-dioxa-6-silaundeca-2,9-diyne
2,2,4,4,14,14-hexamethyl-7,7,9,9,11,11-hexaphenyl-1,3,8,10-tetraoxa-2,9-disilacyclotetradeca-5,12-diyne
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