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Purity:99%
InChI:InChI=1/C44H34N8/c45-29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(46)12-4-26)37-21-23-39(51-37)44(28-7-15-32(48)16-8-28)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(47)14-6-27/h1-24,49-50H,45-48H2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-
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Presented here is a method for rapidly t...
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pyrrole
4-aminobenzaldehyde
tetrakis(4-aminophenyl)porphyrin
| Conditions | Yield |
|---|---|
|
With
toluene-4-sulfonic acid;
In
N,N-dimethyl-formamide;
|
74% |
|
With
butyric acid;
In
N,N-dimethyl-formamide;
at 60 - 135 ℃;
|
55% |
pyrrole
4-nitrobenzaldehdye
tetrakis(4-aminophenyl)porphyrin
| Conditions | Yield |
|---|---|
|
pyrrole; 4-nitrobenzaldehdye;
With
acetic anhydride;
In
propionic acid;
for 4h;
Reflux;
Inert atmosphere;
With
pyridine;
for 1.5h;
Reflux;
With
hydrogenchloride; tin(ll) chloride;
at 20 - 80 ℃;
for 3h;
|
37% |
|
4-nitrobenzaldehdye;
With
acetic anhydride; propionic acid;
at 80 ℃;
pyrrole;
at 135 ℃;
for 0.5h;
Further stages;
|
15.1% |
|
pyrrole; 4-nitrobenzaldehdye;
With
acetic anhydride;
In
acetic acid;
With
hydrogenchloride; tin(ll) chloride;
|
|
|
pyrrole; 4-nitrobenzaldehdye;
With
hydrogenchloride; acetic acid; tin(ll) chloride;
at 65 ℃;
|
|
|
pyrrole; 4-nitrobenzaldehdye;
With
acetic anhydride; propionic acid;
for 3h;
Reflux;
With
hydrogenchloride; tin(II) chloride dihdyrate;
|
5,10,15,20-tetrakis(4-nitrophenyl)porphyrin
pyrrole
4-nitrobenzaldehdye
zinc(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine
tetrakis(4-bentaineamidophenyl)porphyrin
5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin
5,10,15,20-tetrakis(p-fluorophenyl)porphyrin
5,10,15,20-tetra-(4-chlorophenyl)porphyrin
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