Purity:99%
|
General Description |
9-Oxabicyclo[6.1.0]non-4-ene is an epoxide. It undergoes halofluorination reactions with N-halosuccinimides and triethylamine tris-hydrofluoride or Olah′s reagent. |
InChI:InChI=1/C8H12O/c1-2-4-6-8-7(9-8)5-3-1/h1-2,7-8H,3-6H2/b2-1-/t7-,8-/m0/s1
Polymers that can be chemically recycled...
Fused and bridged compounds of Formula (...
Bridged compounds of Formula (I) and For...
Bioorthogonal chemistry holds great pote...
cyclo-octa-1,5-diene
![(Z)-9-oxabicyclo[6.1.0]non-4-ene](/upload/2026/5/f83a0ad2-5105-4e53-b8e1-95c4282e8bd3.png)
(Z)-9-oxabicyclo[6.1.0]non-4-ene
| Conditions | Yield |
|---|---|
|
With
m-chloroperoxybenzoic acid;
In
tetrahydrofuran; chloroform;
at 20 ℃;
for 42h;
Inert atmosphere;
|
51% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; chloroform;
at 20 ℃;
for 42h;
Inert atmosphere;
|
51% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 4h;
Inert atmosphere;
|
44% |
|
With
dihydrogen peroxide;
at 80 ℃;
for 40h;
|
1,5-cis,cis-cyclooctadiene
(Z)-9-oxabicyclo[6.1.0]non-4-ene
| Conditions | Yield |
|---|---|
|
With
3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; chloroform;
at 20 ℃;
for 18h;
|
90% |
|
With
dihydrogen peroxide; chloroformic acid ethyl ester;
|
87% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -80 ℃;
Inert atmosphere;
|
84% |
|
With
dihydrogen peroxide; magnesium sulfate;
methyltrioxorhenium(VII);
In
tert-butyl alcohol;
at 0 ℃;
for 1.5h;
|
80% |
|
With
peracetic acid; sodium acetate;
In
chloroform;
at 50 ℃;
for 2h;
RT, 24 h;
|
72% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
Ambient temperature;
|
70% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
at 0 - 20 ℃;
for 12h;
|
62% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
|
60% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
for 4h;
Ambient temperature;
|
59% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
at 0 - 20 ℃;
for 12h;
|
54% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
at 0 - 20 ℃;
for 12h;
|
54% |
|
With
tert.-butylhydroperoxide;
In
decane;
at 80 ℃;
for 4h;
Green chemistry;
|
51% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
at 0 ℃;
for 12h;
|
46% |
|
With
molybdenyl acetylacetonate; oxygen;
at 90 ℃;
for 4h;
|
42% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
1.) 0 deg C, 2 h, 2.) RT, 1 h;
|
40% |
|
With
dihydrogen peroxide;
silica gel; iron(II) sulfate;
In
chloroform;
at 31 ℃;
for 12h;
|
37% |
|
With
2,3,4,5,6-pentafluoroperoxybenzoic acid; sodium carbonate;
In
dichloromethane;
at 25 ℃;
for 0.1h;
|
|
|
With
sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
Ambient temperature;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
|
|
|
With
dihydrogen peroxide;
aluminum oxide; iron(II);
In
acetonitrile;
at 30 ℃;
for 24h;
|
50 % Spectr. |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
|
|
|
With
1H-imidazole; sodium periodate;
Merrifield resin-supported manganese porphyrin catalyst;
In
water; acetonitrile;
at 20 ℃;
for 36h;
|
76 % Chromat. |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -78 - 20 ℃;
Inert atmosphere;
|
|
|
With
1-butyl-3-methylimidazolium phosphotungstate; dihydrogen peroxide;
In
water; acetonitrile;
at 50 ℃;
for 24h;
|
41 %Chromat. |
|
With
3-chloro-benzenecarboperoxoic acid;
|
|
|
With
2,6-dichloropyridine N-oxide; carbonyl(1,4,8,11,15,18,22,25-octadodecylphthalocyaninato)ruthenium(II);
In
toluene;
at 90 ℃;
for 24h;
Reagent/catalyst;
Catalytic behavior;
Inert atmosphere;
|
34 %Chromat. |
|
With
isobutyraldehyde;
In
acetonitrile;
at 35 ℃;
for 5h;
|
44 %Chromat. |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -20 ℃;
for 12h;
|
1,5-cis,cis-cyclooctadiene
Trans-2-fluorocyclooct-5-en-1-ol
trans-8-iodo-cyclooct-4-en-1-yl acetate
cyclo-octa-1,5-diene
Cyclooctene oxide
trans-trans-2,5-di-iodo-9-oxabicyclo<4.2.1>nonane
endo,endo-2,6-diiodo-9-oxa-bicyclo[3.3.1]nonane
(Z)-oct-4-enedial
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